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Wiswesser's rule : ウィキペディア英語版
Wiswesser's rule

The Wiswesser rule gives a simple method to determine the energetic sequence of the atomic subshells (n,l). n is the principal quantum number and l is the azimuthal quantum number. The energetic sequence of the subshells characterized by the quantum numbers (n,l) is the sequence that leads to a monotonous increasing row of function values for the Wiswesser-function.
:W(n,l) = n + l - \left( \frac \right)
For example: if n = 2 and l = 1, this correspondents with an 2p-orbital.
If the results of this function for each shell and subshell are ordered, the resulting sequence is: 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p...
To illustrate this, the corresponding values of each of these shells can be found in the table below:
We can now clearly see that the Aufbau principle and Wiswesser's Rule come to the same order of filling electron shells.
==See also==

* Atomic orbital energy
* Aufbau principle
* Electron configuration

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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